4.7 Review

Progress in graphene-based magnetic hybrids towards highly efficiency for microwave absorption

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Article Chemistry, Physical

Phenolic resin reinforcement: A new strategy for hollow NiCo@C microboxes against electromagnetic pollution

Liru Cui et al.

Summary: The study successfully synthesized hollow NiCo@C microboxes through alkaline etching and phenolic resin (PR) reinforcement using NiCo Prussian blue analog (PBA) microcubes as the precursor. The PR modification stabilized the microstructure during high-temperature pyrolysis and regulated the chemical composition simultaneously, promising the microboxes a bright prospect as potential candidates against electromagnetic pollution.

CARBON (2021)

Article Chemistry, Physical

Ferrero Rocher® chocolates-like FeCo/C microspheres with adjustable electromagnetic properties for effective microwave absorption

Ruiyang Tan et al.

Summary: In this study, FeCo/C microspheres were synthesized using a two-step hydrothermal method, with electromagnetic parameters effectively adjusted by controlling the reaction time. This resulted in excellent microwave absorption properties at a low filling ratio.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Facile synthesis of nitrogen-doped reduced graphene oxide/nickel ferrite hybrid nanocomposites with superior electromagnetic wave absorption performance in the X-band

Ruiwen Shu et al.

Summary: Nitrogen-doped reduced graphene oxide/nickel ferrite hybrid nanocomposites were synthesized by a one-pot hydrothermal method. The additive volumes of hydrazine hydrate and filler loadings significantly influenced the electromagnetic wave absorption properties, with optimal performance of 54.4 dB reflection loss and 4.5 GHz absorption bandwidth achieved.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

In situ construction of hierarchical core-shell Fe3O4@C nanoparticles-helical carbon nanocoil hybrid composites for highly efficient electromagnetic wave absorption

Yongpeng Zhao et al.

Summary: In this study, a novel composite of helical carbon nanocoils (CNCs) and Fe3O4@C core-shell structures was successfully synthesized, with different morphologies and multilevel heterostructural interfaces obtained by controlling the preparation process parameters. The composite exhibited excellent microwave absorption performance at a relatively thin thickness, and expanded the effective frequency range.

CARBON (2021)

Article Chemistry, Physical

Sandwich-like sulfur-free expanded graphite/CoNi hybrids and their synergistic enhancement of microwave absorption

Yuanyuan Yao et al.

Summary: Sulfur-free expanded graphite (EG) was prepared by chemical oxidation, then EG-based cobalt-nickel alloy hybrid (EG@CoNi) was obtained via hydrothermal method in this work. The incorporation of CoNi particles enhanced the soft magnetization of EG@CoNi hybrids, resulting in improved dielectric loss and microwave absorption characteristics. The synergy and double-loss mechanism between CoNi nanoparticles and EG contributed to the well impedance matching and electromagnetic wave attenuation of the hybrids.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Materials Science, Multidisciplinary

Facile synthesis of lightweight 3D hierarchical NiCo2O4 nanoflowers/reduced graphene oxide composite foams with excellent electromagnetic wave absorption performance

Ning Sun et al.

Summary: A 3D hierarchical NiCo2O4 nanoflowers/reduced graphene oxide (NiCo2O4/RGO) composite foam was successfully synthesized in this study, showing highly efficient electromagnetic wave absorption performance with low reflection loss at thin thickness and broad frequency bandwidth coverage.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Physical

Constructing multiple heterogeneous interfaces in the composite of bimetallic MOF-derivatives and rGO for excellent microwave absorption performance

Yazhen Zhao et al.

Summary: The study prepared CoNi@NCPs-rGO structure using ZIF-67@CoNi LDHs-GO precursor, with rGO significantly enhancing the absorption performance of EMWs absorber. The compound shows excellent absorption performance at 10.62 GHz, with an effective absorption bandwidth of up to 4.03 GHz.

CARBON (2021)

Article Chemistry, Physical

Biomass-derived graphene-like porous carbon nanosheets towards ultralight microwave absorption and excellent thermal infrared properties

Huanqin Zhao et al.

Summary: Developing ultralight microwave absorbers with good heat-insulating properties is crucial for modern society. Graphene-like porous carbon nanosheets derived from waste pomelo peel exhibit superior thermal insulation and microwave absorption properties. The unique 2D morphology and high porosity contribute to their excellent performance.

CARBON (2021)

Article Chemistry, Physical

Cellulose-based Ni-decorated graphene magnetic film for electromagnetic interference shielding

Gaojie Han et al.

Summary: A flexible and ultrathin CNF/TRGO@Ni film with enhanced electrical conductivity and EMI shielding effectiveness has been successfully fabricated in this study. The film maintains only a 7.5% decline in electrical conductivity and EMI SE after being bent 1000 cycles due to its excellent mechanical flexibility. The EMI shielding mechanism is attributed to the combination of enhancing impedance mismatch, multireflection in brick-mortar lamellar structure, and endowing synergetic loss by graphene and Ni nanoparticles.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

FeNi nanoparticles embedded reduced graphene/nitrogen-doped carbon composites towards the ultra-wideband electromagnetic wave absorption

Hongxia Zhang et al.

Summary: A unique rGO/N-C/FeNi hybrid with excellent EM wave absorption performance was successfully synthesized, with the rGO/N-C/FeNi-3 hybrid showing the best performance, with a minimum reflection loss value of -68.87 dB.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Review Materials Science, Multidisciplinary

A review on recent advances in carbon-based dielectric system for microwave absorption

Liru Cui et al.

Summary: The development of carbon-based dielectric systems has brought about a new frontier in absorbing materials, as the combination of carbon materials and other dielectric components can produce superior microwave absorption performance compared to traditional magnetic materials.

JOURNAL OF MATERIALS SCIENCE (2021)

Article Chemistry, Applied

Chain-like Fe3O4@void@mSiO2@MnO2 composites with multiple porous shells toward highly effective microwave absorption application

Mingtao Qiao et al.

Summary: High-efficiency microwave absorbers are in heavy demand due to the development of 5G technology. The chain-like Fe3O4@void@mSiO(2)@MnO2 composites show promising microwave absorption properties with multiple porous shells. The introduction of hierarchical MnO2 shells contributes to improving the absorption performance, while the construction of multiple porous shells benefits broadband microwave absorption.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

Article Materials Science, Composites

Reduced graphene oxide/Fe2O3 hollow microspheres coated sponges for flexible electromagnetic interference shielding composites

Kuan-Yu Chen et al.

Summary: In this study, low-density, compressible and porous composites were fabricated by coating PU sponge with rGO and Fe2O3, achieving high EMI shielding effectiveness through enhanced absorption and dielectric loss, as well as utilizing the porous structure for multiple reflections and scattering of EM waves. By selectively stacking rGO coated and rGO/Fe2O3 coated sponges, the absorption of electromagnetic waves was further improved up to 97.3% by serving as reflection and absorption layers.

COMPOSITES COMMUNICATIONS (2021)

Article Chemistry, Physical

A novel multi-cavity structured MOF derivative/porous graphene hybrid for high performance microwave absorption

Shangwei Song et al.

Summary: Carbon materials have potential as lightweight microwave absorbers, but their performance is limited by single loss mode. The novel ZnO/ZnFe2O4/C@PG composites, synthesized using metal organic framework and porous graphene network, show promising microwave absorption performance with multiple reflection and scattering.

CARBON (2021)

Article Chemistry, Physical

Ti3C2Tx/rGO porous composite films with superior electromagnetic interference shielding performances

Yali Zhang et al.

Summary: The novel method of preparing Ti3C2Tx-based porous EMI shielding composite films with the assistance of graphene oxide resulted in dense surface and porous inside structure, leading to improved EMI shielding effectiveness. The Ti3C2Tx/rGO porous composite films showed superior thermal stability and electrical conductivity, with the potential for application in ultra-thin, light, and flexible EMI shielding materials.

CARBON (2021)

Article Chemistry, Physical

Lightweight graphene aerogels by decoration of 1D CoNi chains and CNTs to achieve ultra-wide microwave absorption

Biao Zhao et al.

Summary: Hybrid graphene aerogels decorated with 1D CoNi chains and CNTs exhibit strong microwave absorption properties, with optimal reflection loss value of -50.8 dB and effective absorption bandwidth of 8.5 GHz. The enhanced microwave absorption is attributed to high ohmic loss, multiple polarization, and eddy current loss induced by a 3D macroscopic conductive network. The GA-CNT-CoNi aerogel is considered a promising candidate for microwave absorption due to its characteristics of ultra-low filler content, strong absorption, ultra-wideband, small thickness, and lightweight.

CARBON (2021)

Article Chemistry, Physical

Achieving super-broad effective absorption bandwidth with low filler loading for graphene aerogels/raspberry-like CoFe2O4 clusters by N doping

Xiangyu Wang et al.

Summary: The study presents a CFO/N-rGA composite material with a super-broad microwave absorption bandwidth and low reflection loss. The high-efficiency microwave absorption of the composite material is attributed to enhanced polarization relaxation, specific design of the conductive network, and superior impedance matching.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Materials Science, Multidisciplinary

Polymer-bubbling for one-step synthesis of three-dimensional cobalt/carbon foams against electromagnetic pollution

Fengyuan Wang et al.

Summary: Constructing three-dimensional foam-like structures in magnetic metal/carbon composites through a nitrate assisted polymer-bubbling strategy allows for the regulation of properties and microstructure. By manipulating the weight ratio of cobalt nitrate and polymer, the electromagnetic properties of the composites can be easily controlled to achieve superior microwave absorption performance.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Materials Science, Multidisciplinary

Magnetic coupling engineered porous dielectric carbon within ultralow filler loading toward tunable and high-performance microwave absorption

Wang Yang et al.

Summary: A strategy to construct hierarchical porous carbon with embedded Ni nanoparticles for microwave absorption applications is proposed, demonstrating excellent performance with ultralow filler loading. The material achieved a minimum reflection loss of -72.4 dB and a broad absorption bandwidth of 5.0 GHz. This work opens up new avenues for the development of high-performance and lightweight MA materials.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Materials Science, Multidisciplinary

Synthesis of covalently bonded reduced graphene oxide-Fe3O4 nanocomposites for efficient electromagnetic wave absorption

Xudong Liu et al.

Summary: The high-performance electromagnetic wave absorbers, covalently bonded reduced graphene oxide-Fe3O4 nanocomposites, demonstrated excellent absorption properties with Fe3O4 nanoparticles successfully grafted onto graphene by amide bonds. The synergistic effect between dielectric and magnetic loss, good attenuation ability, and excellent impedance matching contribute to the outstanding electromagnetic wave absorption performance. Furthermore, covalent bonds act as carrier channels to facilitate electron migration and enhance the absorption performance of the absorbers.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Nanoscience & Nanotechnology

Lightweight, Flexible Cellulose-Derived Carbon Aerogel@Reduced Graphene Oxide/PDMS Composites with Outstanding EMI Shielding Performances and Excellent Thermal Conductivities

Ping Song et al.

Summary: By dissolving cotton in a NaOH/urea solution, cellulose aerogels were obtained and further processed to prepare cellulose carbon aerogels@reduced graphene oxide aerogels. The resulting composites showed excellent EMI shielding effectiveness, thermal stability, and thermal conductivity, making them promising for lightweight and flexible EMI shielding applications.

NANO-MICRO LETTERS (2021)

Article Chemistry, Physical

Rational construction of porous N-doped Fe2O3 films on porous graphene foams by molecular layer deposition for tunable microwave absorption

Shichao Zhao et al.

Summary: A hybrid architecture of porous graphene foams and nitrogen-doped porous Fe2O3 films was successfully fabricated using molecular layer deposition (MLD), significantly enhancing microwave absorption performance with an approximately 8-fold increase in minimum reflection loss value.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

Tailoring conductive network nanostructures of ZIF-derived cobalt-decorated N-doped graphene/carbon nanotubes for microwave absorption applications

Kaifeng Wang et al.

Summary: This study focuses on the development of microwave absorption materials with optimized dielectric and magnetic loss properties, utilizing Co-ZIF-67 as a self-template for the growth of N-doped graphene/carbon nanotube conductive networks. By adjusting ingredient proportions and calcination temperature, diverse microwave absorption performances can be achieved. The nanostructures significantly impact the microwave absorption performance, offering a promising pathway for designing and optimizing prospective microwave absorbers.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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A review on carbon/magnetic metal composites for microwave absorption

Baolei Wang et al.

Summary: Developing high-efficiency microwave absorption materials is crucial for solving electromagnetic pollution issues, with carbon/magnetic metal composites being promising candidates for high-performance microwave absorbers. Understanding the mechanisms of microwave absorption and exploring the preparation methods and properties of these composites indicate great potential for the future development of high-performance microwave absorption materials.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

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Magnetic ferrite/carbonized cotton fiber composites for improving electromagnetic absorption properties at gigahertz frequencies

Sateesh Bandaru et al.

Summary: This study demonstrates a bio-derived ferrite/carbon material with optimized microwave absorption properties, showing a potential for solving electromagnetic problems in the Gigahertz frequency range. The structure-performance relationships in dielectric-magnetic materials are explored, providing insights for future microwave absorber design approaches.

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Rationally designed hierarchical N-doped carbon nanotubes wrapping waxberry-like Ni@C microspheres for efficient microwave absorption

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