期刊
FOOD SCIENCE AND BIOTECHNOLOGY
卷 25, 期 1, 页码 33-40出版社
KOREAN SOCIETY FOOD SCIENCE & TECHNOLOGY-KOSFOST
DOI: 10.1007/s10068-016-0005-y
关键词
GC-ECD; matrix effect; solvent calibration; matrix-matched calibration; recovery rate
Matrix effects observed during the multiresidue analysis of seven organochlorine pesticides in six different agricultural products with GC-ECD were assessed. The presence of matrix coextractives, a major cause of observed matrix effects, directly and/or indirectly influenced the chromatographic responses of some pesticides. Two types of external calibrations, solvent calibration (SC) and matrixmatched calibration (MC), were used to assess matrix effects. Greater matrix effects were observed at the lower concentrations of each pesticide. The extent of matrix effects varied unpredictably with matrix type. Among the analyzed pesticides, iprodione, cyhalothrin, and cypermethrin exhibited greater matrix effects (> 150%) for almost all matrices. The pesticide recovery rates obtained with MC were not statistically different from a 100% recovery rate in most samples, which indicates that MC may diminish the overestimates occurred due to matrix effects in GC analysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据