4.7 Article

Stretchable graphene and carbon nanofiber capacitive touch sensors for robotic skin applications

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ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2021.05.048

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Graphene; Carbon nanofiber; Electrical properties; Nanocomposites; Morphology; Touch sensor

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Stretchable capacitive tactile sensors were fabricated using conductive graphene nanoplatelets (GNPs) or carbon nanofibers (CNFs) coatings on stretchable nitrile rubber sheets. CNF-based coatings showed lower sheet resistance and better current transmission under elongation compared to GNP-based coatings. Structural damages within the coatings could be healed by a rapid heat annealing process, restoring to initial current.
Stretchable capacitive tactile sensors are crucial for the current and future soft robotic technology, particularly for designing artificial electronic skin for robots. In this study, we fabricated stretchable electronic tactile sensors by spray coating of conductive graphene nanoplatelets (GNPs) or carbon nanofibers (CNFs) with liquid natural rubber (NR) binder over stretchable nitrile rubber (NBR) sheets. CNF-based coatings showed remarkably low sheet resistance of 30 Omega sq(-1) and much better current transmission patterns under elongation, with similar to 50% current transmission reduction under 50% elongation, compared to GNP-based coatings with 600 Omega sq(-1) resistance and similar to 99% current transmission reduction under 50% elongation. Structural damages/cracks within the coatings due to repeated stretch-release cycles could be healed by a rapid convective heat annealing process, restoring to initial current. Haptic sensing properties of the fabricated flexible capacitive device based on CNFs-coated nitrile rubber were evaluated by connecting it to a printed circuit board (PCB). The device could easily sense tactile forces from tens of mN to a few N, corresponding to (10(-2)-10) kPa pressure range over curvilinear surfaces or under elongation. (C) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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