Integrated sensing array of the perovskite-type LnFeO3 (Ln=La, Pr, Nd, Sm) to discriminate detection of volatile sulfur compounds

Distinguishing toxic gases among the various volatile sulfur compounds (VSCs) is of significant practical value for atmospheric and environmental pollution monitoring, industrial monitoring, and even for medical diagnostics (where VSCs are indicators of diseases). The particular challenge lies in the detection and discrimination of sulfur-containing gases such as dimethyl disulfide (DMDS), methyl sulfide (DMS), hydrogen sulfide (H2S), and carbon disulfide (CS2) is of value. Herein, single-phase perovskite-type LnFeO(3) nanoparticles were prepared by the citrate sol-gel method. Their gas sensing characteristics regard to the four typical VSCs were investigated. We found that the gas response of the p-type semiconductor LnFeO(3) gas sensors to the four typical VSCs are significantly different. In addition, the sensors offer high performance, good tolerance to environmental changes and long-term stability for detecting VSCs gas at an operating temperature of 210 degrees C. A new design of sensor array was realized by integrating a series of LnFeO(3) materials, which revealed excellent recognition ability for various VSCs, showing promise for real time monitoring.

Automated summary

The single-phase perovskite-type LnFeO(3) nanoparticles prepared by the citrate sol-gel method exhibit significant differences in gas response to the four typical VSCs, showing good performance, tolerance to environmental changes, and long-term stability for detecting VSCs gas at an operating temperature of 210 degrees C. A new sensor array design integrating a series of LnFeO(3) materials shows excellent recognition ability for various VSCs, promising real-time monitoring capabilities.