4.7 Article

Defect engineering-induced porosity in graphene quantum dots embedded metal-organic frameworks for enhanced benzene and toluene adsorption

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Summary: The study focused on enhancing the adsorption of volatile organic compounds (VOCs) under high humidity conditions by implanting hydrophobic short-chain polyethylene glycol (PEG) into MIL-101(Cr). The addition of PEG resulted in the formation of new hydrophobic pores that significantly improved adsorption capacity and diffusivity for toluene while reducing those for water. The breakthrough curve showed a 3.3 times increase in toluene working capacity on PEG(5)@MIL-101 at 80% RH compared to pristine MIL-101(Cr).

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