Ultrasonic power combined with seed materials for recovery of phosphorus from swine wastewater via struvite crystallization process

Recovering P via struvite crystallization is an effective way to utilize the resources in swine wastewater. At present, the main challenges of traditional struvite crystallization process are the long reaction time and insufficient removal efficiency. In this study, a novel method to promote struvite crystallization process through ultrasound (US) combined with seed materials is proposed to overcome these defects. We systematically study the effects of US, seed materials, and ultrasonic power on nutrient recovery. The experimental results show that under the conditions of pH 9.5 and MgCl2:P molar ratio1.4:1, the addition of 2 g/L pre-synthesized struvite as the seed materials can increase the P removal rate to 91.56%, whereas, the addition of 80 W ultrasonic power for 15 min can make the P removal rate reach 94.18%. Meanwhile, the combination of US and struvite seed crystals can achieve a maximum P removal efficiency value of 97.66% in which 10 min for the reaction time is enough. The products are characterized using XRD, SEM, and FTIR to determine the phosphorus removal mechanism of ultrasonic power combined with seed induction. The shearing effect of US is found beneficial to affect the surface morphology of the seed crystals, which provides more nucleation sites to enhance crystal nucleation and growth. The removal efficiency comparison reveals that this combined technology performs an excellent removal effect.

Automated summary

Recovering phosphorus from swine wastewater via struvite crystallization is effective, but faces challenges of long reaction times and low removal efficiency. This study proposes a novel method of using ultrasound combined with seed materials to promote struvite crystallization, which significantly enhances phosphorus removal efficiency. Characterization of the products reveals that the combined technology provides excellent removal effects by affecting crystal nucleation and growth.