期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 598, 期 -, 页码 314-323出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.04.039
关键词
W; O emulsion; Droplet size; Fat crystallization; NMR diffusometry
资金
- Fund for Scientific Research - Flanders (FWOVlaanderen) - Hercules foundation
This study compared solid-fat based W/O emulsions with liquid-oil based W/O emulsions and found that water diffusion in solid-fat based W/O emulsions is hindered, leading to more accurate determination of water droplet size. The solid fat matrix may hinder extra-droplet water diffusion by increasing the tortuosity of the diffusive path.
Hypothesis: It is expected that low resolution (LR) NMR diffusometry enables (more) accurate water droplet size determination for solid-fat based water-in-oil (W/O) emulsions with (sub)-micron size water droplets in comparison to liquid-oil based W/O emulsions due to hindered extra-droplet water diffusion. Experiments: W/O emulsions with a volume-weighed mean diameter of about 1 mm and a solid fat content (SFC) ranging from 0% to 74% were produced. The aqueous phase contained the ionic marker tetraphenylphosphonium chloride (TPPCl). The water droplet size was estimated using LR and high resolution (HR) NMR diffusometry. Findings: HR-NMR diffusometry showed that the diffusion behavior of water and TPPCl was different, indicating water diffusion beyond the droplet's interfacial boundaries. From a certain SFC onwards, a slower echo decay was observed for the water molecules, thus decreasing the overestimation of the waterdroplet size in (sub)micron W/O emulsions. For those emulsions, the solid fat matrix is believed to hinder extra-droplet water diffusion, which is most likely to be related to the increased tortuosity of the diffusive path in the porous fat crystal network. Using LR-NMR, it can be verified whether the water echo attenuation is mono-exponential or bi-exponential by increasing the gradient pulse duration for the maximum gradient strength, which is more convenient for routine analysis compared to HR-NMR. (c) 2021 Elsevier Inc. All rights reserved.
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