期刊
FOOD CHEMISTRY
卷 213, 期 -, 页码 485-493出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2016.06.115
关键词
Cyclodextrin-assisted liquid-solid extraction; Electrochemical detection; Jujube; Phenolic compounds; Quadrupole time-of-flight tandem mass spectrometry; Ultrahigh performance liquid chromatography
资金
- National Natural Science Foundation of China [81573552]
- Zhejiang Provincial Natural Science Foundation of China [LY15H280016]
- Hangzhou social development of scientific research projects [20150533B05]
- Young and Middle-Aged Academic Leaders of Hangzhou [2013-45]
- National Undergraduate Training Program for Innovation and Entrepreneurship [201510346020]
- New-shoot Talents Program of Zhejiang Province [2015R423032]
A novel, simple and environmental friendly sample preparation technique based on the use of cyclodextrin has been developed for the extraction of phenolic compounds from jujube samples, the analytes being finally determined by ultrahigh performance liquid chromatography with electrochemical detection. Quadrupole time-of-flight tandem mass spectrometry was used to characterize the composition of jujube fruit. The present method exhibited higher efficiency for extracting phenolic compositions than Pharmacopoeia heat-reflux approach in term of peak areas. Moreover, compared with traditional ultrasound-assisted extraction, the developed methodology was found without the use of toxic organic solvent, meeting the principles of green chemistry. Validation experiments showed that the proposed method presented good linearity (r(2) > 0.9970), satisfactory precision (RSD < 7.55%), and high recovery (85.63-105.67%). The limits of detection were from 4.92 ng/mL to 142.85 ng/mL for eight phenolic compounds. Eventually, the optimized approach was successfully applied to the analysis of jujube fruit. (C) 2016 Elsevier Ltd. All rights reserved.
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