期刊
JOURNAL OF CLEANER PRODUCTION
卷 316, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2021.128136
关键词
Hydroxylamine; Nano micro-electrolysis material; Fenton-like degradation; Rhodamine B
资金
- Research and Development and Demonstration of Integrated Treatment Tech-nology for Water Environmental Pollution in River Basins (Major science and technology projects of Jilin province) [20200503003SF]
- Key Lab of Water Resources and Environment of Jilin Province
- Key Laboratories of the Ministry of Education
- Jilin University
The study investigated the degradation of Rh B using the nMET/H2O2 system with a preference for HA. Results showed that under near-neutral pH conditions, the addition of specific concentrations of H2O2, HA, and nMET can achieve 100% degradation efficiency of Rh B.
Heterogeneous Fenton-like oxidation is a promising method in dealing with organic pollutants. So far, the interaction of the nano micro-electrolysis material (nMET) and hydroxylamine (HA) Fenton-like system still needs to be explored. A HA-favored degradation of rhodamine B (Rh B) with nMET/H2O2 system was investigated in this paper. The influences of various experimental factors, as well as reuse and universal adaptability of the catalyst and the intermediates were comprehensively assessed. Under the near-neutral pH condition, the degradation efficiency of Rh B was up to 100% with H2O2 (1 mM), HA (0.1 g/L) and nMET (0.03 g/L) at 8 min, which was ascribed to the iron ions leaching and accelerated Fe(III)/Fe(II) recycle by the promotion of HA. As confirmed by the Electron paramagnetic resonance (EPR) and quenching experiments tests, singlet oxygen (O-1(2)) and hydroxyl radical (center dot OH) were the predominant reactive oxygen species (ROS) for the degradation of Rh B molecules in nMET/H2O2/HA system, then the potential mechanism of ROS generation and pathway of Rh B degradation were proposed. This study furnishes a novel perspective for ROS generation from the micro electrolysis function, proving that nMET is feasible for the efficient degradation of organic contaminants in heterogeneous Fenton-like system.
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