Electronic spectroscopy of Mg-phthalocyanine embedded in cold hydrogen clusters produced by a pulsed nozzle

Cold clusters of molecular hydrogen were created using a pulsed nozzle. The thermodynamical states of the clusters were characterized by measuring the cluster beam velocity and the laser-induced fluorescence (LIF) spectra of embedded molecules. Two distinct velocity components were identified in the beam that originates from different clustering mechanisms. The fast velocity component corresponds to the expansion of H-2 from the gas phase, while the slow velocity component corresponds to the expansion from the liquid phase. The velocity distribution of these two components showed no significant difference between the expansions of para and normal hydrogen. In this study, LIF spectroscopy of single Mg-phthalocyanine molecules embedded in the H-2 clusters consisting of 10(5) H-2 molecules was used to investigate the properties of the fast component. The observed peak frequencies of the LIF signals, compared to those observed in helium droplets, were used to infer the possible presence of the liquid phase in the fast component of the H-2 clusters below 5 K. The shift, linewidth, and splitting in the spectra, which strongly depend on the ortho/para ratio, are attributed to the local configurations of hydrogen in the vicinity of the probe molecules. Published under an exclusive license by AIP Publishing.

Automated summary

Cold clusters of molecular hydrogen were created using a pulsed nozzle, and their thermodynamical states were characterized by measuring cluster beam velocity and laser-induced fluorescence (LIF) spectra. Different velocity components originating from different clustering mechanisms were identified, with the possibility of the presence of a liquid phase in the clusters below 5K.