期刊
JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷 66, 期 8, 页码 2942-2958出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jced.0c01052
关键词
-
资金
- National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2019K1A4A7A03113187]
- National Research Foundation of Korea [2019K1A4A7A03113187] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The densities and viscosities of three solutions were measured and various volumetric and viscometric characteristics were calculated to explain the experimental results. The properties were analyzed through intermolecular interactions and molecular structures to determine the viscous flows of the solutions. The obtained thermodynamic properties can be utilized in the design and optimization of a CO2-capture process.
The densities and viscosities of three solutions, namely, two binary solutions [triethylenetetramine (TETA) + H2O and TETA + 2-amino-2-methyl-1-propanol (AMP)] and one ternary solution (TETA + AMP + H2O) were measured at atmospheric pressure and in the temperature range of 303.15 to 343.15 K. Their viscometric and volumetric characteristics, such as the excess molar volume (V-E), partial molar volume (V-i), excess partial molar volume (V-i(E)), partial molar volume at infinite dilution (V-i(infinity)), excess partial molar volume at infinite dilution (V-i(E,infinity)), apparent molar volume (V-phi.i), viscosity deviation (Delta eta), molar Gibbs free energy (Delta G), molar entropy (Delta S), and molar enthalpy (Delta H), were calculated to determine the viscous flows of the solutions, and they could also explain the empirical results theoretically. The degrees of the decrease in viscosities and densities of the solutions were different. The variations in the properties were also analyzed through their intermolecular interactions and molecular structures. Additionally, Delta eta and V-E were obtained by the Redlich-Kister model, for the binary solutions, and the Cibulka model, for the ternary solution. With the given standard deviations, sigma <= 3.55, for the binary solutions, and sigma = 3.98, for the ternary solution, the viscosity data were parameterized by the Eyring-non-random two-liquid model. The obtained thermodynamic properties were reliable and could be employed in the design and optimization of a CO2-capture process, utilizing the studied solutions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据