期刊
JOURNAL OF CATALYSIS
卷 398, 期 -, 页码 123-132出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2021.04.018
关键词
Platinum electrodes; Oxygen reduction reaction; Hydrogen peroxide reduction reaction; Single crystal surfaces; Effect of the surface structure
资金
- Ministerio de Ciencia e Innovacion [PID2019-105653 GB-100]
- Generalitat Valenciana [PROMETEO/2020/063]
The HPRR on Pt surfaces was studied at pH = 13, showing that Pt(1 1 1) is the most active surface, but its activity decreases with the introduction of steps. Inhibition of HPRR was observed at low potentials, with the onset potential controlled by OHads and the point of maximum entropy. Experiments with different rotation rates suggested the formation of an HPRR intermediate linked to the inhibition process.
The hydrogen peroxide reduction reaction (HPRR) is investigated at pH = 13 on the Pt basal planes and stepped surfaces with (1 1 1) terraces separated by either monatomic (1 0 0) or (1 1 0) steps. A quantitative analysis of the surface structure effect revealed that Pt(1 1 1) is the most active surface and its activity progressively decreases when steps are introduced. Additionally, inhibition of the HPRR is observed at low potentials, which onset potential is governed by the OHads and the point of maximum entropy (pme) of the interphase. Experiments with different rotation rates suggest the formation of an HPRR intermediate linked to the inhibition process, which is more strongly adsorbed on (1 1 0) than (1 0 0) steps. Finally, a comparison of the HPRR and ORR (oxygen reduction reaction) illustrated the important differences for both reactions, which are dependent on the step density. These divergences have been discussed based on adsorbed intermediates and O-2 interactions with the Pt surface. (C) 2021 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据