期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 867, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.159153
关键词
Lithium-ion batteries; Electrolyte; Additive; Ni-rich NCM cathode; Allyl phenyl sulfone
资金
- National Research Foundation of Korea (NRF) [NRF-2019R1C1C1002249]
- Technology Innovation Program [20011905]
- Ministry of Trade, Industry & Energy (MOTIE, Korea)
Introducing allyl phenyl sulfone (APS) functional electrolyte additive can effectively enhance the cycling performance of nickel-rich layered lithium metal oxides at high temperature, leading to improved overall electrochemical performance of a cell.
Nickel-rich layered lithium metal oxides have been on the spotlight for their being advanced cathode materials for lithium-ion batteries; however, their poor cycling performance at high temperature is a critical bottleneck in their application. To improve the interfacial stability of Ni-rich layered lithium metal oxides, we propose the use of a functional electrolyte additive, allyl phenyl sulfone (APS), which is modified by allyl and sulfone functional groups. The sulfone functional group introduced into cathode-electrolyte inter-phases (CEI) is anticipated to effectively suppress electrolyte decomposition during cycling, whereas the allyl functional group renders the CEI more durable as its desirable chemical reactivity promotes additional crosslinking reaction between CEI. Additionally, the allyl functional group selectively scavenges fluoride (F-) species in a cell and is thus is expected to reduce F- concentration, leading to the improved overall electrochemical performance of a cell. Results of ex-situ nuclear magnetic resonance spectroscopy confirmed that the APS additive effectively reduced the F- species via a chemical scavenging reaction. As regards the cycling performance of a half-cell, the cell cycled with the APS additive exhibited a considerably improved cycling retention at high temperature (78.9%), whereas the cell cycled with standard electrolyte suffered from continuous fading of retention (64.3%). (C) 2021 Elsevier B.V. All rights reserved.
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