期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 867, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.158805
关键词
Magnetostriction; CeFe11Ti; Magneto-crystalline anisotropy; Hard magnetic materials
资金
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [405553726, TRR 270, 316912154]
- future pioneering program development of magnetic material technology for high-efficiency motors (MagHEM) by the New Energy and Industrial Technology Development Organization (NEDO)
This study investigated the formation and magnetic properties of ThMn12-type Ce1+xFe11Ti samples, revealing the formation of twin boundaries and achieving grain refinement by adjusting chemical composition and annealing temperatures. The magnetostrictive behavior of the CeFe11Ti-phase was also studied, showing an M-2 behavior near the Curie temperature. Additionally, magnetic characterizations under hydrostatic pressure and after hydrogenation demonstrated a slight reduction in anisotropy field, consistent with the observed increase for the hydrogenated compound.
The criticality of rare-earth elements and its impact on the permanent magnet market have initiated a search for alternative material systems, either to fill the magnetic performance gap between ferrites and Nd-Fe-B magnets or to even replace the existing benchmark systems. Ce-based systems are attractive due to the abundance of cerium, however the formation of secondary phases leads to challenges for Ce-based compounds. We investigated the formation and magnetic properties of ThMn12-type Ce1+xFe11Ti samples for x = 0.15 and 0.20 compositions. Microstructural investigations reveal the formation of twin boundaries in the ThMn12 grains with a misorientation angle of 58 degrees +/- 2 degrees. By varying the chemical composition and lowering the annealing temperatures, a grain refinement and reduction in twin boundary density was achieved. In addition, the magnetostrictive characteristic of CeFe11Ti-phase was investigated. Around the Curie temperature, an M-2 behaviour is noted, in contrast to an M-3 behaviour at lower temperatures. To probe the effect of unit cell compression and expansion on the magnetic properties, magnetic character-izations were carried out under hydrostatic pressure and after hydrogenation. A slight reduction is observed for the measured anisotropy field under 0.45 GPa hydrostatic pressure in the temperature interval of 10-300 K, which is consistent with the small increase detected for the hydrogenated compound. (C) 2021 Elsevier B.V. All rights reserved.
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