4.6 Article

Superhydrophobic Myristic Acid/TiO2-Nickel Coating with Improved Corrosion Inhibition Property Created by Facile Electrodeposition and Modification Methods

期刊

JOM
卷 73, 期 10, 页码 3111-3120

出版社

SPRINGER
DOI: 10.1007/s11837-021-04814-8

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资金

  1. Natural Science Foundation of Chongqing [cstc2020jcyj-msxmX0826]
  2. Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan province [2021CL15]
  3. Research Project on Higher Education Teaching Reform of Chongqing Three Gorges University [JGYB2108]
  4. Undergraduate Training Program for Innovation and Entrepreneurship of Chongqing Three Gorges University [2021010]
  5. Science and Technology Research Program of Chongqing Municipal Education Commission [KJQN201901228, KJQN201901223, KJQN202001234]

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This article investigates the construction of nickel coating on brass substrate using electrodeposition technique and modification with MTC modifier. The modified Ni coatings show strong durability, self-cleaning, superhydrophobicity, and improved corrosion resistance. This electrodeposition-modification route holds potential for preparing superhydrophobic surfaces on metallic materials.
In this article, nickel (Ni) coating was constructed on brass substrate by a simple electrodeposition technique, and myristic acid/TiO2 composite (MTC) modifier was used to modify Ni coating. The chemical composition and surface morphology of MTC confirm that myristic acid (MA) was successfully grafted on TiO2 nanoparticles. As a comparison, the structures of the Ni coatings were modified by MTC or MA. We found that both modified Ni coatings exhibit strong durability, self-cleaning and superhydrophobicity ability and have good prospect of decontamination. After Ni coating had been modified by MTC, the water contact angle and sliding angle of MTC-Ni were > 170 degrees and < 5 degrees, respectively. In addition, the MTC-Ni coating shows improved corrosion resistance, which can effectively retard the corrosion of brass. This novel and facile electrodeposition-modification route is believed to be widely applied to preparing superhydrophobic surfaces on metallic materials.

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