期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 46, 期 58, 页码 30061-30078出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.06.136
关键词
Rate equation theory; Gas-solid reaction; Chemical kinetics; Product layer diffusion; Mg hydrogenation
资金
- National Natural Science Foundation of China [51976102]
- Sichuan Province University Science and Technology Cooperation [2020ZYD081]
The traditional shrinking-core model with a uniform solid product layer is insufficient to predict the kinetic transition behavior of H2 adsorption reactions. This study proposes a new model based on the inward growth of solid products on the solid surface, which shows improved prediction accuracy for various Mg-based materials. The model can also be used to analyze intraparticle diffusion and the impact of particle microstructure changes.
A uniform solid product layer normally assumed in the shrinking-core model cannot predict the kinetic transition behavior of the H2 adsorption reactions. In this study, the concept of a uniform solid product layer has been replaced by that of the inward growth of solid products on the solid surface. A rate equation is established to calculate the inward growth of the solid product and was implemented into the shrinking-core model to calculate the H2 adsorption kinetics for various shapes of Mg-based materials. The prediction accuracy of the developed model is verified from the detailed experimental data. To account for the external gas diffusion around the particle and the intraparticle gas diffusion, an analytical equation is derived using the Thiele modulus method. This model can be used to analyze various kinetic aspects and to analyze the effect of change in the particle microstructure on intraparticle diffusion. (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据