期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 46, 期 52, 页码 26457-26465出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.05.147
关键词
Amorphous FeOOH; Hollow nanosphere; Anode material; Sodium ion batteries
资金
- National Natural Science Foundation of China [21701144]
The FeOOH@C composite synthesized in this study showed good cycling life and high-rate performance, indicating its potential to be a candidate for electrode material of sodium ion batteries.
Sodium ion batteries (SIBs) have enjoyed a high profile in recent years and gradually been commercialized to supplement the lithium-ion batteries system. However, the large volume expansion of anode materials within discharging and low electrical conductivity hinder the application of SIBs. In this work, a FeOOH@C composite was synthesized with the use of hydrothermal method and pyrolyzing of polydopamine. The amorphous FeOOH exhibits a hollow spherical structure to offer free space for buffering the volumetric variation. Furthermore, the outer carbon served as a protective shell could maintain the sphere integrity and enhance the electrical conductivity. Hence, benefiting from the achieved synergy of the hollow architecture, amorphous structure and carbon shell, the composite presented a long cycle life (316 mA h g(-1) after 500 cycles at a current density of 100 mA g(-1) and 234.5 mA h g(-1) after 400 cycles at 2 A g(-1)) and high-rate performance (180 mA h g(-1) at 5 A g(-1)), revealing a potential to be a promising candidate for electrode material of SIBs. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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