Efficient nickel catalyst with preferred orientation and microsphere for direct borohydride fuel cell

Ni catalysts with preferred orientation and microsphere were fabricated by a facile onestep pulsed voltage electrodeposition (PVE) method, while the crystal plane orientation and catalytic activity for borohydride oxidation reaction (BOR) were researched systematically. The results indicate that adjusting pulse anode potential can effectively regulate the morphology and crystal plane preferred orientation of Ni catalysts. The optimal NiPVE0.15 catalyst exhibits the highest catalytic activity, stability, and fuel efficiency to BOR. The improvement of catalytic activity of Ni and fuel efficiency is attributed to the more exposure of the (220) crystal plane, which blocks the competing hydrogen evolution reaction (HER), increases the intrinsic activity of the catalytic sites to BOR, and strengthens the adsorption of escaping hydrogen to further electrooxidation. Meanwhile, the no-cracks feature of the microsphere increases the active sites and avoids the shedding of catalysts.

Automated summary

In this study, Ni catalysts with preferred orientation and microsphere structure were fabricated using a simple one-step pulsed voltage electrodeposition method, and their crystal plane orientation and catalytic activity towards borohydride oxidation reaction (BOR) were systematically investigated. The results showed that adjusting the pulse anode potential can effectively control the morphology and crystal plane orientation of Ni catalysts. The optimal NiPVE0.15 catalyst exhibited the highest catalytic activity and fuel efficiency.