Constitutive modeling of magneto-viscoelastic polymers, demagnetization correction, and field-induced Poynting effect

Magneto-active polymers are polymer-based composites consisting of magnetizable micro-particles embedded in an elastomeric matrix material. The presence of magnetic particles provides strong tunability to the stiffness and damping properties of the polymeric composites under the magnetic field. We propose here a novel free energy-based phenomenological modeling for magneto-active polymers. Coupled mechanical and magnetization constitutive equations are derived by considering magneto-viscoelasticity in a finite deformation framework. The model calibration takes into account the demagnetization effect, which depends on the specimen size, shape, and its own magnetization. The model prediction is verified with the available experimental data. Finally, a coupled simple shear problem is solved to demonstrate the influence of magnetic field on the Poynting effect. Classical nonlinear soft elastic material shows positive Poynting effect, i.e., shearing planes try to expand. We found the possibilities of field-induced reverse or negative Poynting effect in shear for magneto-active polymers. Such a negative Poynting effect could potentially affect a very diverse range of applications from the performances of miniature sensors and actuators to controlled drug delivery. (C) 2021 Elsevier Ltd. All rights reserved.

Automated summary

Magneto-active polymers are polymer-based composites with magnetizable micro-particles that offer tunability to stiffness and damping properties under a magnetic field. A novel free energy-based model has been proposed to derive coupled mechanical and magnetization constitutive equations. The model calibration considers demagnetization effects and the potential for field-induced reverse or negative Poynting effect in shear for magneto-active polymers.