期刊
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
卷 45, 期 15, 页码 21170-21181出版社
WILEY
DOI: 10.1002/er.7170
关键词
2D nanosheet; 3D flower; energy storage; hybrid supercapacitor; ternary metal oxides
资金
- Ministry of Trade, Industry and Energy [20004958]
Constructing hierarchically structured porous electroactive materials, such as ternary nickel cobalt molybdenum oxide (NCMO), shows great potential for high-performance hybrid supercapacitors (HSCs). The NCMO electrode exhibits larger specific capacitance compared to other metal oxide electrodes, and optimizing the mass ratio of NCMO//AC HSCs can lead to high energy and power densities with excellent capacitance retention over cycles.
Constructing electroactive materials with hierarchically structured porous architecture is promising for developing various energy storage electrodes. In particular, the transition metal complexes with this archistructure are potential toward the fabrication of high-performance hybrid supercapacitors (HSCs) due to the rational design and its peculiar Faradic battery-type charge storage behavior. Herein, we report the hierarchically structured microflowers of ternary nickel cobalt molybdenum oxide (NCMO) assembled by ultrathin nanosheets via a hydrothermal process and the subsequent calcination. The interconnected open network and abundant void space of hierarchically structured flower-like NCMO are associated with improved electrochemical performance. Consequently, the obtained NCMO electrode achieves the larger specific capacitance (C-s) of 1696 F g(-1) at 1 A g(-1) than the nickel molybdenum oxide (NMO; 878 F g(-1)), cobalt molybdenum oxide (CMO; 690 F g(-1)), NiO (350 F g(-1)), and Co3O4 (259 F g(-1)) electrodes, respectively. The electrochemical performances of HSCs, configured using the hierarchically structured ternary NCMO microflower and activated carbon (AC), respectively, are optimized by varying mass ratios of two electrodes. In particular, the NCMO//AC HSCs with 1:3 (D13) mass ratio exhibit the maximum energy and power densities of 51.22 W h kg(-1) and 41.67 kW kg(-1) with the high-capacitance retention of 89.29% over 20 000 cycles.
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