4.7 Article

A 2D metal-organic framework interpenetrated by a 2D supramolecular framework assembled by CH/π interactions

期刊

INORGANIC CHEMISTRY COMMUNICATIONS
卷 130, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.inoche.2021.108705

关键词

Hetero-interpenetrating framework; Metal-organic framework; Supramolecular framework; CH/pi interaction; Magnetism

资金

  1. NSF of China [21871262, 21805257, 21901242]
  2. NSF of Fujian Province [2019J01130, 2020J05080]
  3. NSF of Xiamen [3502Z20206080]
  4. Recruitment Program of Global Youth Experts

向作者/读者索取更多资源

A new compound with an interesting twofold 2D + 2D -> 3D hetero-interpenetrating framework was successfully synthesized at room temperature. The framework is built from a 2D metal–organic framework and a 2D supramolecular framework assembled by CH/pi interactions, which interact with each other by strong pi center dot center dot center dot pi stacking and CH/pi interactions.
A new compound, formulated as [(Cu2Cu2Cl6)-Cu-I-Cl-II(L)(TCNB)](n)center dot(MeOH)(n)(acetone)(n) (1) (L = tris(2-naphthimidazolylmethyl) amine, TCNB = 1,2,4,5-tetracyanobenzene), featuring an interesting twofold 2D + 2D -> 3D hetero-interpenetrating framework was synthesized at room temperature. The framework is built from a 2D metal-organic framework and a 2D supramolecular framework assembled by CH/pi interactions, which inclined interpenetrate and interact with each other by strong pi center dot center dot center dot pi stacking and CH/pi interactions.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据