期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 130, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.inoche.2021.108705
关键词
Hetero-interpenetrating framework; Metal-organic framework; Supramolecular framework; CH/pi interaction; Magnetism
资金
- NSF of China [21871262, 21805257, 21901242]
- NSF of Fujian Province [2019J01130, 2020J05080]
- NSF of Xiamen [3502Z20206080]
- Recruitment Program of Global Youth Experts
A new compound with an interesting twofold 2D + 2D -> 3D hetero-interpenetrating framework was successfully synthesized at room temperature. The framework is built from a 2D metal–organic framework and a 2D supramolecular framework assembled by CH/pi interactions, which interact with each other by strong pi center dot center dot center dot pi stacking and CH/pi interactions.
A new compound, formulated as [(Cu2Cu2Cl6)-Cu-I-Cl-II(L)(TCNB)](n)center dot(MeOH)(n)(acetone)(n) (1) (L = tris(2-naphthimidazolylmethyl) amine, TCNB = 1,2,4,5-tetracyanobenzene), featuring an interesting twofold 2D + 2D -> 3D hetero-interpenetrating framework was synthesized at room temperature. The framework is built from a 2D metal-organic framework and a 2D supramolecular framework assembled by CH/pi interactions, which inclined interpenetrate and interact with each other by strong pi center dot center dot center dot pi stacking and CH/pi interactions.
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