期刊
INORGANIC CHEMISTRY
卷 60, 期 16, 页码 11745-11749出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c00284
关键词
-
资金
- Guangdong Basic and Applied Basic Research Foundation [2020B1515120036]
- National Natural Science Foundation of China [51708252]
A vapor-phase grafting strategy is developed for the postsynthetic modification of metal-organic frameworks (MOFs), resulting in carboxylated MOFs with well-maintained structures and improved fluoride removal performance.
A vapor-phase grafting strategy is developed for the postsynthetic modification of metal-organic frameworks (MOFs). On the basis of the Schotten-Baumann reaction between acyl chloride (-COCl) and amino (-NH2) groups and hydrolysis of -COCl, the carboxylated MOFs could be prepared through simple exposure in vaporized acyl chloride molecules and immersion in water. The modified MOFs have well-maintained crystalline structures and porosities and show substantially improved fluoride removal performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据