期刊
INORGANIC CHEMISTRY
卷 60, 期 13, 页码 9282-9286出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c01658
关键词
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资金
- Natural Science Foundation of China [21863009]
- Natural Science Foundation of Ningxia Province [2020AAC02005]
- Special Fund of Shaanxi Key Laboratory of Special Fuel Chemistry and Material [SPCF-SKL-2020-0008]
- Open Foundation of State Key Laboratory of Coordination Chemistry [SKLCC2005]
- Discipline Project of Ningxia [NXYLXK2017A04]
- Graduate Innovative Experiment [GIP2020013]
The self-assembly of high-energy nitrogen-rich linkers with nontoxic alkali-metal lithium/sodium results in four new solvent-free EMOFs with unparalleled decomposition temperature and heats of detonation, making the 3D Li(I)-EMOF a superheat-resistant explosive candidate.
Energetic metal-organic frameworks (EMOFs) are very promising as heat-resistant explosives, affording both thermal stability and energy properties. In this work, the self-assembly of high-energy nitrogen-rich linkers with nontoxic alkali-metal lithium/sodium leads to four new solvent-free EMOFs. Because of unparalleled decomposition temperature (T-dec = 403 degrees C) and heats of detonation (3.475 kcal.g(-1)), a 3D Li(I)-EMOF can be considered to be a superheat-resistant explosive candidate.
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