A Microporous MOF Constructed by Cross-Linking Helical Chains for Efficient Purification of Natural Gas and Ethylene

Natural gas (NG) and ethylene (C2H4) are two raw materials of significant value for manufacturing versatile fine chemicals and/or polymers, and thus the development of solid adsorbing agents such as metal-organic frameworks (MOFs) applied to their depuration is very crucial but remains highly challenging. In this research, we designed and synthesized a ligand containing mixed N and O coordination donors, which was solvothermally assembled with Cu(II) ions to generate a microporous MOF. X-ray crystallography revealed that the title MOF incorporates one-dimensional (1D) homochiral helical chains that are datively cross-linked to form open channels in the three-periodic coordination framework. Furthermore, the behaviors of C-1-C-2 hydrocarbons and carbon dioxide (CO2) adsorbed in the title MOF were systematically investigated, revealing its promising potential for the purification of both NG and C2H4. At 109 kPa and 298 K, the C-2/methane (CH4), CO2/CH4, and acetylene (C2H2)/C2H4 adsorption selectivities are impressive, reaching as high as 62.9, 28.6, and 3.5, respectively. This work represents a unique MOF based on cross-linked homochiral helical chains exhibiting dual-function separation potentials for NG and C2H4 purifications.

Automated summary

The study presented a microporous MOF designed and synthesized with Cu(II) ions, which showed promising potential for adsorbing and purifying natural gas and ethylene. The MOF exhibited impressive selectivities for C-2/methane, CO2/methane, and acetylene/ethylene adsorption, highlighting its dual-function separation capabilities.