期刊
INORGANIC CHEMISTRY
卷 60, 期 15, 页码 10958-10969出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c00619
关键词
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资金
- Ramsay Memorial Trust
- UCL Chemistry
- EPSRC [EP/R511638/1, EP/L017709]
The mechanism of aluminum-mediated hydroboration of terminal alkynes was investigated using novel aluminum complexes with symmetric and asymmetric ligands. Kinetic analysis and stoichiometric reactions revealed that the mechanism likely proceeds via the initial formation of an Al-borane adduct. Additionally, the most unstable aluminum complex was found to promote the decomposition of the substrate, leading to catalysis of the reaction.
The mechanism of the aluminum-mediated hydroboration of terminal alkynes was investigated using a series of novel aluminum amidinate hydride and alkyl complexes bearing symmetric and asymmetric ligands. The new aluminum complexes were fully characterized and found to facilitate the formation of the (E)-vinylboronate hydroboration product, with rates and orders of reaction linked to complex size and stability. Kinetic analysis and stoichiometric reactions were used to elucidate the mechanism, which we propose to proceed via the initial formation of an Al-borane adduct. Additionally, the most unstable complex was found to promote decomposition of the pinacolborane substrate to borane (BH3), which can then proceed to catalyze the reaction. This mechanism is in contrast to previously reported aluminum hydride-catalyzed hydroboration reactions, which are proposed to proceed via the initial formation of an aluminum acetylide, or by hydroalumination to form a vinylboronate ester as the first step in the catalytic cycle.
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