4.7 Article

Antiparallel Coupling between a 4f System and a Photoexcited Cyclic π System in a Dysprosium(III) Monoporphyrinato Complex

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Summary: The study investigated the intramolecular magnetic interaction between a localized open-shell 4f-electronic system and a photoexcited macrocyclic p-conjugate system in a terbium-phthalocyaninnato 1:1 complex. Results showed that the Tb ion's 4f electron system is magnetically coupled with the photoexcited p-conjugate system of the phthalocyaninato macrocycle.

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