4.7 Article

Synthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)2

期刊

INORGANIC CHEMISTRY
卷 60, 期 19, 页码 15041-15047

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c02547

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资金

  1. Natural Science Foundation of Hubei Province [2019CFB569, 2020CFB430]
  2. Science and Technology Foundation for Creative Research Group of Hubei Normal University [2019CZ08]
  3. Alexander von Humboldt Foundation through a Humboldt fellowship

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A new alkali metal-rare earth metal anhydrous sulfate, KTb(SO4)(2) (KTSO), was synthesized using a hydrothermal method. Its crystal structure, optical properties, and band gap structure were studied, providing insights for further exploration of new anhydrous sulfates. The compound exhibits a second-order nonlinear optical effect and its birefringence values were in good agreement with calculations.
A new alkali metal-rare earth metal anhydrous sulfate, KTb(SO4)(2) (KTSO), was synthesized by a hydrothermal method. It crystallized in the non-centrosymmetric (NCS) orthorhombic space group P2(1)2(1)2(1) with cell parameters a = 5.43950(10), b = 8.8579(3), c = 13.3962(4), Z = 2. Its structure is composed of [KO11], [TbO8], and [SO4] groups, which are interconnected to constitute a one-dimensional (1D) chain, and then further linked to construct a three-dimensional (3D) network structure through [SO4] units. The results of the powder frequency doubling test show that KTb(SO4)(2) has a phase-matching secondorder nonlinear optical effect of 0.3 times that of KH2PO4 (KDP). The measured birefringence of the crystal (0.01) agrees well with the calculated value (0.019). Meanwhile, its infrared and ultraviolet spectrum and thermal properties were studied, respectively. Its optical properties and band gap structure are studied by theoretical calculation. This work provides a NCS structure of anhydrous sulfates and offers guidance for further exploration of new anhydrous sulfates.

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