4.7 Article

Low-pressure hydrothermal processing of mixed polyolefin wastes into clean fuels

期刊

FUEL
卷 294, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2021.120505

关键词

Low-pressure hydrothermal processing; Mixed polyolefin waste; Polyethylene; Polypropylene; Clean gasoline; Clean diesel

资金

  1. School of Engineering Technology
  2. Davidson School of Chemical Engineering at Purdue University

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A new low-pressure hydrothermal processing method has been developed to convert polyolefin waste into clean oils with high yield, which can be further distilled into gasoline and diesel. This method saves a significant amount of energy and reduces greenhouse gas emissions compared to conventional production methods.
The amount of polyolefin waste, which is 63% of the total plastic waste, has grown exponentially over the past six decades. Its degradation products pose a serious threat to ecosystems and human health. Polyolefins can be converted to clean oils or fuels by using the supercritical water liquefaction (SWL) method at high pressures (>23 MPa), which require high capital and energy costs. A new low-pressure (-2 MPa) hydrothermal processing (LP-HTP) method is developed to convert polyolefin waste with 50% or more polypropylene into oils with 87% yield at 450 ?C and 45 min. The oils, which are C4 to C25 hydrocarbons, can be distilled into clean gasoline and ultra-low sulfur diesel. With this method, up to 190 million tons of fuels can be produced annually from polyolefin waste, resulting in savings of 92% of the energy and 71% of the GHG emissions compared to conventional methods for producing fuels.

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