4.7 Article

Enhanced photocatalytic activity of Cu2O for visible light-driven dye degradation by carbon quantum dots

期刊

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 29, 期 6, 页码 8613-8622

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-021-16337-5

关键词

Carbon quantum dots; Cuprous oxide; Photocatalytic degradation; Antibacterial activity

资金

  1. National Natural Science Foundation of China-Union Foundation of Henan [U1704170]
  2. Henan Normal University [QD18083]
  3. Key Programs for Science and Technology Development in Henan Province [192102310300]
  4. Key Scientific Research Project of Henan Ministry of Education [20A610005, 21A180015]

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Cuprous oxide (Cu2O), a p-type semiconductor material, has been found to play a significant role in photocatalysis, and enhancing its photocatalytic activity can be effectively achieved by introducing CQDs, leading to improved degradation of methylene blue and antibacterial activity against Escherichia coli.
Cuprous oxide (Cu2O), a p-type semiconductor material, plays an important role in photocatalysis, which has narrower band gap (similar to 2.1 eV), abundant availability, and low toxicity. However, the applications of Cu2O are mainly restricted by its high recombination rate and low charge collection. Hence, it is of great significance to fmd an efficient method to improve the photocatalytic activity of Cu2O. In this work, the CQDs-loaded Cu2O nanocomposites (CQDs/Cu2O) were successfully obtained via hydrothermal method. It was worth noting that the CQDs/Cu2O nanocomposite displayed improved photocatalytic activity compared to that of pure Cu2O with a lower dosage (25 mg) under visible light, which could completely degrade the methylene blue in 8 min. The recycling experiments also showed that the photocatalytic activity still remained up to 90% after 8 cycles. In addition to the photodegradation of methylene blue, the CQDs/Cu2O nanocomposite also had an excellent antibacterial activity against Escherichia coli (100%, 30 min). These results demonstrated that introducing CQDs to Cu2O was a feasible method to improve the photocatalytic performance of Cu2O.

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