Effect of heat treatment on the photocatalytic activity of α-Fe2O3 nanoparticles: towards diclofenac elimination

alpha-Fe2O3 nanoparticles were synthesized via a straightforward method. XRD, FTIR, SEM, ESR, and DRS techniques investigated the influence of various calcination temperatures on the crystal structure, optical, and photocatalytic properties of the samples. The obtained results demonstrated that the average crystallite size increased with the increase in the calcination temperature. Measured and computed optical properties were in accordance and the bandgap energy decreased with the increase in the calcination temperature. The highest photocatalytic degradation efficiency for diclofenac (DCF) was obtained with the sample calcinated at 300 degrees C (96%). The photocatalytic process occurs because of the presence of OH center dot radicals. The addition of H2O2 led to the inhibition of OH center dot radicals that H2O2 scavenged.

Automated summary

Alpha-Fe2O3 nanoparticles were synthesized using a straightforward method, and the influence of various calcination temperatures on crystal structure, optical, and photocatalytic properties was investigated. Results showed that the average crystallite size increased with higher calcination temperatures, and the bandgap energy decreased correspondingly. The highest photocatalytic degradation efficiency was achieved with a sample calcinated at 300 degrees C, attributed to the presence of OH· radicals in the photocatalytic process.