Interactions between magnetic particles and polyaluminum chloride on the coagulation behavior in humic acid-kaolin synthetic water treatment

Understanding the interactions between magnetic particles (MPs) and polyaluminum chloride (PACl) is essential to elucidate the magnetic seeding coagulation (MSC) process. However, little is known about how MPs interact with the different Al species coexisting in the PACl. Here, the relationships among pollutants removal, residual Al distribution, and floc properties were comparatively studied in the MSC and traditional coagulation (TC) processes to address this issue. The response surface analysis indicated that the interaction between PACl and MPs dosages exhibited significant effects on turbidity and DOC removal. Negligible changes of dissolved Al after MPs addition indicated the weak connection between Ala and MPs. The formation of MPs-Alb-HA complexes resulted in the increase of turbidity removal from 90.2% to 96.0% and the reduction of colloidal Al from 0.67 to 0.30 mg L-1. Humic-like components could be adsorbed on MPs forming MPs-HA complexes, which enhanced the DOC removal from 55% to 58.5%. MPs addition produced loose flocs with a small floc fractal dimension value (1.74), so the average size and strength of flocs in the MSC process (425 mu m and 49.7%) were lower than that in the TC process (464 mu m and 58.3%). The cumulative volume percentage of large flocs (>700 mu m) was decreased from 29.7% to 20.7% with MPs addition, indicating the disruption of large flocs and the reproduction of more fragments. The effective separation of these fragments by magnetic attraction maintained the efficient coagulation performance. This study provides new insights into the interaction mechanism of MPs and PACl in the MSC process.

Automated summary

The interaction between PACl and MPs dosages has significant effects on pollutant removal and turbidity reduction. The weak connection between Ala and MPs, along with the formation of MPs-Alb-HA complexes, enhances the removal efficiency of turbidity and dissolved Al in water treatment processes.