期刊
ENVIRONMENTAL POLLUTION
卷 285, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2021.117251
关键词
Microplastic; Marine debris; Near-infrared hyperspectral imaging; SWIR hyperspectral imaging; Machine learning
资金
- National Institute of Advanced Analytical Sciences and Tech-nologies (INCTAA) [FAPESP 2014/50951-4]
- CNPq [465768/2014-8]
- [PROEX-CAPES-001]
This study presents a high throughput screening method for automatic identification of microplastics in beach sand using near-infrared hyperspectral imaging. By utilizing chemometric models and comprehensive spectral dataset, the method demonstrated high sensitivity and specificity in classifying various types of microplastics, with potential for comprehensive microplastic-type characterization screening.
Microplastic pollution is a global concern theme, and there is still the need for less laborious and faster analytical methods aiming at microplastics detection. This article describes a high throughput screening method based on near-infrared hyperspectral imaging (HSI-NIR) to identify microplastics in beach sand automatically with minimum sample preparation. The method operates directly in the entire sample or on its retained fraction (150 mu m-5 mm) after sieving. Small colorless microplastics (<600 mu m) that would probably be imperceptible as a microplastic by visual inspection, or missed during manual pick up, can be easily detected. No spectroscopic subsampling was performed due to the high-speed analysis of line-scan instrumentation, allowing multiple microplastics to be assessed simultaneously (video available). This characteristic is an advantage over conventional infrared (IR) spectrometers. A 75 cm2 scan area was probed in less than 1 min at a pixel size of 156 x 156 mu m. An in-house comprehensive spectral dataset, including weathered microplastics, was used to build multivariate supervised soft independent modelling of class analogy (SIMCA) classification models. The chemometric models were validated for hundreds of microplastics (primary and secondary) collected in the environment. The effect of particle size, color and weathering are discussed. Models' sensitivity and specificity for polyethylene (PE), polypropylene (PP), polyamide-6 (PA), polyethylene terephthalate (PET) and polystyrene (PS) were over 99% at the defined statistical threshold. The method was applied to a sand sample, identifying 803 particles without prior visual sorting, showing automatic identification was robust and reliable even for weathered microplastics analyzed together with other matrix constituents. The HSI-NIR-SIMCA described is also applicable for microplastics extracted from other matrices after sample preparation. The HSI-NIR principals were compared to other common techniques used to microplastic chemical characterization. The results show the potential to use HSI-NIR combined with classification models as a comprehensive microplastic-type characterization screening.
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