4.3 Article

Pore structure characteristics and fractal structure evaluation of medium- and high-rank coal

期刊

出版社

SAGE PUBLICATIONS INC
DOI: 10.1177/01445987211034315

关键词

Coal; pore structure characterization; fractal structure; specific surface area; adsorption and desorption; experiment of liquid nitrogen

资金

  1. Key Project of University Humanities and Social Science in Anhui Province [SK2019A0102]
  2. Program for State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal Mines [SKLMRDPC20ZZ02]
  3. Program for Innovative Research Team of Huainan Normal University [XJTD202001]
  4. Program of Hefei Technology College [2021KJB16]
  5. University Outstanding Young Talents Project of Anhui Province [gxyq2021270]

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This research investigated the pore structure characteristics of medium- and high-rank coal and evaluated their fractal structure. Samples were collected from different coalfields, analyzed using various methods, and classified into five grades based on fractal dimension analysis. The results of fractal evaluation were consistent with curve analysis and pore size analysis.
The presence of gas content in medium- and high-rank coal poses a threat to safety production. Safe gas extraction is based on a correct understanding of the pore structure of coal. This work investigates the pore structure characteristics of medium- and high-rank coal and evaluates their fractal structure. The coal samples were collected from Huainan Coalfield and Qinshui Coalfield, and divided into four types, according to the difference in surface bright characteristics. Through adopting low-temperature liquid nitrogen adsorption and desorption, and applying Kelvin equation, we obtain the main pore structure types and main pore size distribution characteristics of various coal briquettes. Electron microscope scanning structure and scientific analysis were used for special adsorption and desorption curves and hysteresis to find the dynamic reason. According to the different adsorption mechanism and Frenkel-Halsey-Hill-based model, with P/P-0 = 0.4 as the dividing point of fractal dimension analysis, the pore structure of coal samples is classified into five grades. The fractal evaluation results are consistent with the results of curve analysis and pore size analysis.

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