4.7 Review

A Mini-Review on the Advances in the Kinetic Understanding of the Combustion of Linear and Cyclic Oxymethylene Ethers

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Article Thermodynamics

Inhibiting and promoting effects of NO on dimethyl ether and dimethoxymethane oxidation in a plug-flow reactor

Hao Zhang et al.

Summary: The study investigates the effects of NO addition on the low-temperature oxidation of DME and DMM, revealing an inhibiting effect of NO on DME reactivity at low temperatures and a promoting effect at high temperatures. For DMM, a temperature-dependent effect of NO is observed only at high concentrations. NO addition suppresses hydrocarbon intermediates while promoting the formation of specific products for both DME and DMM.

COMBUSTION AND FLAME (2021)

Article Energy & Fuels

Determining the laminar burning velocity of nitrogen diluted dimethoxymethane (OME1) using the heat-flux burner method: Numerical and experimental investigations

Sven Eckart et al.

Summary: Premixed flames are important in combustion systems such as aircraft combustors, gas turbines, and internal combustion engines. Oxygenated fuels like C-1-oxygenate dimethoxymethane have advantages in reducing soot particles in diesel combustion processes.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2021)

Article Thermodynamics

An experimental and kinetic modeling study on the oxidation of 1,3-dioxolane

Alina Wildenberg et al.

Summary: This study investigated the oxidation of 1,3-dioxolane and developed a detailed kinetic model to analyze the reaction pathways involved, showing a preference for ring opening beta-scission pathway in the fuel-in-air case. The findings provide insights into the ignition and combustion characteristics of 1,3-dioxolane, offering valuable information for biofuel production and combustion optimization.

PROCEEDINGS OF THE COMBUSTION INSTITUTE (2021)

Review Energy & Fuels

A Review on CO2 Capture Technologies with Focus on CO2-Enhanced Methane Recovery from Hydrates

Salvatore F. Cannone et al.

Summary: Natural gas is seen as a useful transition fuel to reduce emissions from conventional power plants, particularly when considering the removal of carbon dioxide from hydrates using membrane separation technology. The economic analysis and technical aspects of this process are explored in detail, alongside discussions of other carbon capture methods and long-distance CO2 transportation and storage.

ENERGIES (2021)

Review Energy & Fuels

Higher Alcohol and Ether Biofuels for Compression-Ignition Engine Application: A Review with Emphasis on Combustion Kinetics

Liming Cai et al.

Summary: High molecular weight alcohol and ether fuels, with their advanced autoignition propensities and oxygenated molecular structures, show promise as future fuel candidates for compression-ignition engine applications to enhance combustion efficiencies and reduce pollutant emissions. Produced from lignocellulosic biomass as second-generation biofuels, they offer better CO2 balance and avoid adverse impacts on food supply compared to first-generation biofuel production. Research on their fundamental combustion kinetics and practical applications is crucial for their potential as renewable fuels.

ENERGY & FUELS (2021)

Article Energy & Fuels

The effect of poly(oxymethylene) dimethyl ethers (PODE3) on soot formation in ethylene/PODE3 laminar coflow diffusion flames

Yong Ren Tan et al.

Summary: This study investigates the impact of PODE3 on soot formation in ethylene/PODE3 flames, finding that at low blending levels, PODE3 may actually increase soot formation. Results suggest that sufficient amounts of PODE3 can reduce soot formation, specifically in C2 chemistry systems.
Article Thermodynamics

Construction of reduced oxidation mechanisms of polyoxymethylene dimethyl ethers (PODE1-6) with consistent structure using decoupling methodology and reaction rate rule

Bo Niu et al.

Summary: This study constructs reduced mechanisms for the series of PODE1-6 based on decoupling methodology and reaction rate rule, effectively describing the combustion of long-chain PODEn with no available detailed mechanisms, especially for PODE5-6. The final reduced mechanism consists of 92 species and 389 reactions, showing satisfactory performance under wide operating conditions.

COMBUSTION AND FLAME (2021)

Article Energy & Fuels

Construction of a Reduced Diesel/Polyoxymethylene Dimethyl Ether 3 (PODE3) Reaction Mechanism for Combustion and Emission Analysis

Zheng Jing et al.

Summary: A new compact diesel surrogate/PODE3 chemical kinetic reaction mechanism was established and validated through simplifying the detailed PODE3 reaction mechanism, applying optimization techniques, and verifying with experimental data. This reduced mechanism showed accurate prediction and applicability for 3-D computational fluid dynamics (CFD) studies.

ENERGY & FUELS (2021)

Review Energy & Fuels

A critical insight review on homogeneous charge compression ignition engine characteristics powered by biofuels

Pajarla Saiteja et al.

Summary: The depletion of fossil fuels and the significant exhaust emission from conventional engines are the main concerns in the current auto industry. Improving engine performance and reducing emissions are crucial, with advanced combustion mode engines playing a significant role in internal combustion engines' emission control.
Article Energy & Fuels

Experimental and numerical study on the effect of oxymethylene ether-3 (OME3) on soot particle formation

Federica Ferraro et al.

Summary: The study focuses on the impact of oxymethylene ether-3 (OME3) blended with ethylene on carbon particulate formation, indicating a reduction in total number and size of soot particles at various equivalence ratios, with little change in the number of small nanoparticles. The results suggest that OME3 addition may contribute to reducing carbon particulate matter emissions while maintaining the number of small nanoparticles.
Article Thermodynamics

Comparing the pyrolysis kinetics of dimethoxymethane and 1,2-dimethoxyethane: An experimental and kinetic modeling study

Wenyu Sun et al.

Summary: This work investigates the reaction kinetics of the thermal decomposition of DMM and 1,2-DME, with 1,2-DME showing higher reactivity compared to DMM. Different fuel-specific intermediates are observed in the pyrolysis process of each molecule.

COMBUSTION AND FLAME (2021)

Article Energy & Fuels

Property predictions demonstrate that structural diversity can improve the performance of polyoxymethylene ethers as potential bio-based diesel fuels

Danielle L. Bartholet et al.

Summary: A study on polyoxymethylene ethers (POMEs) as potential diesel blendstocks showed that these molecules could significantly reduce soot formation from diesel engines without compromising engine performance or harming the environment.
Review Thermodynamics

Influence of functional groups on low-temperature combustion chemistry of biofuels

Brandon Rotavera et al.

Summary: Ongoing progress in synthetic biology, metabolic engineering, and catalysis has led to the production of diverse advanced biofuels. Understanding the connections between molecular structure and ignition at low temperatures remains a key priority addressed through chemical kinetics modeling. The review highlights the importance of functional groups in influencing chain reactions and the need for further research to address fundamental questions in biofuel ignition.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2021)

Article Chemistry, Medicinal

Atomic Partial Charges as Descriptors for Barrier Heights

Malte Doentgen et al.

JOURNAL OF CHEMICAL INFORMATION AND MODELING (2020)

Article Chemistry, Physical

Temperature- and pressure-dependent kinetics of the competing C-O bond fission reactions of dimethoxymethane

Leonie Golka et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2020)

Review Engineering, Civil

Spray, atomization and combustion characteristics of oxygenated fuels in a constant volume bomb: A review

Peng Zhang et al.

JOURNAL OF TRAFFIC AND TRANSPORTATION ENGINEERING-ENGLISH EDITION (2020)

Article Engineering, Chemical

Production of Oxymethylene Dimethyl Ethers from Hydrogen and Carbon Dioxide-Part I: Modeling and Analysis for OME1

Dominik Bongartz et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Article Engineering, Chemical

Production of Oxymethylene Dimethyl Ethers from Hydrogen and Carbon Dioxide-Part II: Modeling and Analysis for OME3-5

Jannik Burre et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Article Engineering, Chemical

Synthesis of 1,3-Dioxolane from Aqueous Formaldehyde Solution and Ethylene Glycol: Kinetics and Reactive Distillation

Hong Li et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Article Thermodynamics

Influence of fuel-oxygen content on morphology and nanostructure of soot particles

Puneet Verma et al.

COMBUSTION AND FLAME (2019)

Article Energy & Fuels

Autoignition Characteristics of Ethers Blended with Low Cetane Distillates

Andre Nicolle et al.

ENERGY & FUELS (2019)

Article Chemistry, Physical

Heterogeneously catalyzed synthesis of oxymethylene dimethyl ethers (OME) from dimethyl ether and trioxane

Philipp Haltenort et al.

CATALYSIS COMMUNICATIONS (2018)

Article Thermodynamics

Experimental and modeling study of the pyrolysis and combustion of dimethoxymethane

Florence H. Vermeire et al.

COMBUSTION AND FLAME (2018)

Article Thermodynamics

Estimating fuel octane numbers from homogeneous gas-phase ignition delay times

Nimal Naser et al.

COMBUSTION AND FLAME (2018)

Review Green & Sustainable Science & Technology

Liquid biofuels utilization for gas turbines: A review

Ibrahim I. Enagi et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2018)

Review Green & Sustainable Science & Technology

Alcohol and ether as alternative fuels in spark ignition engine: A review

Omar I. Awad et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2018)

Review Engineering, Chemical

Recent Progress in the Production, Application and Evaluation of Oxymethylene Ethers

Kathrin Hackbarth et al.

CHEMIE INGENIEUR TECHNIK (2018)

Article Chemistry, Applied

Gas and soot formed in the dimethoxymethane pyrolysis. Soot characterization

Katiuska Alexandrino et al.

FUEL PROCESSING TECHNOLOGY (2018)

Article Thermodynamics

Pericyclic reactions in ether biofuels

Juan-Carlos Lizardo-Huerta et al.

PROCEEDINGS OF THE COMBUSTION INSTITUTE (2017)

Article Agricultural Engineering

An optimized process design for oxymethylene ether production from woody-biomass-derived syngas

Xiaolei Zhang et al.

BIOMASS & BIOENERGY (2016)

Article Thermodynamics

Dimethoxymethane Oxidation in a Flow Reactor

Lorena Marrodan et al.

COMBUSTION SCIENCE AND TECHNOLOGY (2016)

Article Chemistry, Analytical

Diethyl ether pyrolysis study in a jet-stirred reactor

Nicolas Vin et al.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2016)

Article Engineering, Environmental

Rule-based ab initio kinetic model for alkyl sulfide pyrolysis

Ruben Van de Vijver et al.

CHEMICAL ENGINEERING JOURNAL (2015)

Article Thermodynamics

High temperature oxidation of formaldehyde and formyl radical: A study of 1,3,5-trioxane laminar burning velocities

Jeffrey Santner et al.

PROCEEDINGS OF THE COMBUSTION INSTITUTE (2015)

Article Engineering, Environmental

Environmental impacts of hybrid, plug-in hybrid, and battery electric vehicles-what can we learn from life cycle assessment?

Anders Nordelof et al.

INTERNATIONAL JOURNAL OF LIFE CYCLE ASSESSMENT (2014)

Article Engineering, Chemical

Synthesis of a Green Diesel Fuel Additive Over Cation Resins

Yanyan Zheng et al.

CHEMICAL ENGINEERING & TECHNOLOGY (2013)

Article Chemistry, Physical

A Hierarchical and Comparative Kinetic Modeling Study of C1 - C2 Hydrocarbon and Oxygenated Fuels

Wayne K. Metcalfe et al.

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS (2013)

Article Engineering, Environmental

Genesys: Kinetic model construction using chemo-informatics

Nick M. Vandewiele et al.

CHEMICAL ENGINEERING JOURNAL (2012)

Article Thermodynamics

LEAN AND RICH PREMIXED DIMETHOXYMETHANE/OXYGEN/ARGON FLAMES: EXPERIMENTAL AND MODELING

Veronique Dias et al.

COMBUSTION SCIENCE AND TECHNOLOGY (2010)

Article Chemistry, Physical

Modeling of Rich Premixed C2H4/O-2/Ar and C2H4/Dimethoxymethane/O-2/Ar Flames

Veronique Dias et al.

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS (2009)

Article Chemistry, Physical

Chemical kinetic modeling study of the effects of oxygenated hydrocarbons on soot emissions from diesel engines

CK Westbrook et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2006)

Article Thermodynamics

Chemical kinetic modeling of dimethyl carbonate in an opposed-flow diffusion flame

PA Glaude et al.

PROCEEDINGS OF THE COMBUSTION INSTITUTE (2005)

Article Thermodynamics

Oxidation of dimethoxymethane in a jet-stirred reactor

CA Daly et al.

COMBUSTION AND FLAME (2001)

Article Chemistry, Physical

Kinetics of OH radical reactions with a series of symmetric acetals in the temperature range 293-617 K

C Vovelle et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2001)