4.7 Article

New Battery with Borides as Both Anode and Cathode Materials

期刊

ENERGY & FUELS
卷 35, 期 12, 页码 10315-10321

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.1c01381

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资金

  1. National Natural Science Foundation of China [21473128]

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Transition metal borides Co-B and Co-Ni-B are prepared using a simple chemical reduction method and used to create a new all-boride aqueous solution battery. This battery demonstrates excellent electrochemical performance and extreme frost tolerance, making it suitable for use in cold weather conditions.
Transition metal borides Co-B and Co-Ni-B are prepared by a simple chemical reduction method and used to construct a new all-boride aqueous solution battery with borides used for both the anode and cathode. This all-boride-based battery exhibits an excellent electrochemical property and extreme frost tolerance. The results of the electrochemical performance test demonstrate that the specific capacity of this all-boride battery reaches 332.4 mA h g(-1) at a current density of 500 mA g(-1) and is maintained at 280 mAh g(-1) with a high discharge current density of 8 A g(-1) as a result of the rapid electrochemical reaction kinetics and high electronic conductivity. This all-boride battery can continue to work at low temperatures (-40 degrees C) and exhibits good electrochemical performance; therefore, it can be used under extreme cold weather conditions. The electrode material of the all-boride battery is simple to prepare, is energy-saving, does not require special equipment or a special environment during assembly, and thus shows promise as a new energy storage device.

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