4.6 Article

Is ozone production able to explain the good performance of CabECO® technology in wastewater treatment?

期刊

ELECTROCHIMICA ACTA
卷 396, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2021.139262

关键词

CabECO (R) technology; Electro-ozonizers; Temperature regulation; Ozone production

资金

  1. Spain's Agencia Estatal de Investigacion [PID2019-107271RB-I0 0]
  2. CONACYT [722138]

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This study aims to evaluate the production of ozone with a commercial cell CabECO (R) and investigate factors contributing to its success in disinfecting polluted water. It was found that dosing of oxygen as microbubbles and temperature regulation have positive effects on ozone generation. The results show promising current efficiency with room for further improvements.
This work intends to go a step further in the application of electrochemical technology to produce ozone, by evaluating the production of ozone with a commercial cell registered as CabECO (R), which has been previously used to disinfect heavily polluted water in a successful manner, with a view to ascertaining whether this success may be related to the production of ozone. The CabECO (R) cell is a PEM electrolyzer; that is to say, one in which anode and cathode are connected through a PEM membrane. Since ozone production on the electrolyte is important and depends on the composition of the liquid, attention must be paid to the electrochemical production of scavengers. Dosing of oxygen as microbubbles has a very positive effect on the production of ozone, while temperature regulation is as well considerably important, as the increase in temperature generated by ohmic losses can lead to important decreases in the efficiency of ozone electrogeneration. Rates within the range 0.06-0.60 mg O-3 min(-1) are observed; this means that the maximum current efficiency reached is as high as 6.11% (considering oxygen as raw matter). These results are extremely promising as compared with other references in the literature, at once they also indicate there is room for further improvements and a long way to prevent the effect of scavengers and increase the efficiency of the process. (C) 2021 The Author(s). Published by Elsevier Ltd.

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