期刊
DYES AND PIGMENTS
卷 190, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2021.109320
关键词
Pyrazine; Aggregation-induced emission; Charge transfer; Solvatochromism
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2016R1D1A1B04932654]
A series of pyrazine-based bipodal molecules with multi-stimuli response were synthesized via Suzuki and Sonogashira cross-coupling reactions, showing different optical, thermal, and electrochemical properties depending on modifications to their endcapped donor-acceptor units and ?-conjugation extension. The molecules emit fluorescence from blue to orange depending on the electron-donating substituents, and exhibit solvent-dependent emission with a linear correlation on Dimroth-Reichardt plots. The study also found enhanced emission in aggregates, suggesting potential for developing promising multi-stimuli responsive fluorescent materials.
A series of pyrazine-based bipodal D-?-A-?-D and D-?-A-?-A molecules with multi-stimuli response have been synthesized via Suzuki and Sonogashira cross-coupling reactions. We present a joint theoretical and experimental study to elucidate structure-property relationship of these push-pull chromophores. The modification of the endcapped donor-acceptor units and the extension of ?-conjugation are key factors in tuning their optical, thermal and electrochemical properties. Depending on the different electron-donating substituents, the chromophores emit blue to orange fluorescence. The solvent dependent emission was observed and their Dimroth-Reichardt plots show a linear correlation. The aggregation-induced study shows enhanced emission in aggregates. Our work has elucidated that these small structural isomers can be utilized to develop a promising multi-stimuli responsive fluorescent materials.
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