期刊
CURRENT ORGANIC SYNTHESIS
卷 19, 期 1, 页码 148-165出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570179418666210728145206
关键词
Organocatalysis; organocatalytic process; organocatalytic cascade reactions; asymmetric synthesis; natural products; stereoselec-tivity; catalyst
资金
- Consejo Nacional de Ciencia y Tecnologia [251512]
This review discusses the asymmetric synthesis of different natural products and biologically active compounds in the past decade, focusing on the application of asymmetric organocatalytic reactions and organocatalytic cascade reactions.
Background: The total syntheses of complex natural products have evolved to include new methodologies to save time, simplifying the form to achieve these natural compounds. Objectives: In this review, we have described the asymmetric synthesis of different natural products and biologically active compounds of the last ten years until the current day. Results: An asymmetric organocatalytic reaction is a key to generate stereoselectively the main structure with the required stereochemistry. Conclusion: Even more remarkable, the organocatalytic cascade reactions, which are carried out with high stereoselectivity, as well as a possible approximation of the organocatalysts activation with substrates are also described.
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