4.4 Article

Structure-controllable synthesis of ZnO nanowires using water vapor in an atmospheric-pressure microwave plasma system

期刊

CURRENT APPLIED PHYSICS
卷 28, 期 -, 页码 52-58

出版社

ELSEVIER
DOI: 10.1016/j.cap.2021.05.004

关键词

ZnO nanowire; Atmospheric-pressure microwave plasma; Structure-controllable synthesis; UV sensing

资金

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2018R1D1A1B07048870, 2020R1I1A1A01064345]
  2. National Research Foundation of Korea [2018R1D1A1B07048870, 2020R1I1A1A01064345, 5120201413690] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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By adjusting the microwave input power and water vapor, the aspect ratio of ZnO nanowires can be controlled, allowing for the successful growth of ZnO nanowires with a controllable structure in an atmospheric-pressure microwave plasma system. The morphology of ZnO nanowires is closely related to their sensitivity to UV irradiation and sensing characteristics.
Although the use of atmospheric-pressure microwave plasma to synthesize ZnO nanowires addresses various issues associated with conventional synthesis methods, it is difficult to obtain nanowires with controlled diameters and lengths. Herein, we investigated the effects of microwave input power and water vapor on the structure of ZnO nanowires grown using an atmospheric-pressure microwave plasma system. It was found that the aspect ratio of ZnO nanowires could be controlled by adjusting the plasma temperature and the amount of OH radicals. This method successfully produced ZnO nanowires in a structure-controllable manner with a wide range of aspect ratios from 10 to 340. Interestingly, we found that the sensitivity of the ZnO nanowires to UV irradiation was closely related to the morphology. In particular, the ZnO nanowires with high aspect ratios and densities showed excellent sensing characteristics.

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