期刊
CORROSION SCIENCE
卷 185, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2021.109409
关键词
Ceramic matrix composites; Zirconium; High temperature corrosion; Interfaces
资金
- National Natural Science Foundation of China [51402181]
- Youth Talent Support Program of Shaanxi University of Science and Technology [2016QNBJ08]
- Xi?an Key Laboratory of Green Manufacture of Ceramic Materials Foundation [2019220214SYS017CG039]
The ablation of C/C-ZrC composites at a heat flux of 25 MW/m(2) in a nitrogen plasma torch is characterized by a lower linear ablation rate compared to other composites, mainly due to the formation of ZrN/ZrO2, which blocks chemical reactions and absorbs heat from the plasma jet. Thermochemical ablation, mechanical breakage, and carbon sublimation control the ablation process, with the latter playing a minor role.
Ablation of C/C-ZrC composites was studied at a heat flux of similar to 25 MW/m(2) in a nitrogen plasma torch. C/C-ZrC composites with 4.1 wt% ZrC illustrate a lower linear ablation rate than other composites, that is, 44.7 % lower than that of C/C composites. The formed ZrN/ZrO2 may decrease the ablation rate of the composites by blocking the chemical reaction of the plasma jet and carbon and absorbing significant heat from the plasma jet by their melting and evaporation. The ablation of C/C-ZrC composites is controlled by thermochemical ablation, mechanical breakage, and carbon sublimation, which plays a minor role.
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