期刊
COORDINATION CHEMISTRY REVIEWS
卷 439, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2021.213915
关键词
Metal-organic frameworks; Composites; Electronic conductivity; Ionic conductivity
资金
- National Natural Science Foundation of China [NSFC-U1904215, 21671170, 21901221]
- Changjiang scholars program of the Ministry of Education [Q2018270]
- Natural Science Foundation of Jiangsu Province [BK20190870, BK20200044]
- Six Talent Peaks Project of Jiangsu Province
- Science and Technology Innovation Foster Foundation of Yangzhou University [2016CXJ010]
Metal-organic frameworks (MOFs) have gained increasing attention as porous materials and are widely applied in various fields, but their low conductivity hinders their development. Strategic modulation of the conductive properties of MOFs is needed to achieve optimal performance and broad applications.
As porous materials, metal-organic frameworks (MOFs) have drawn increased attention and are widely applied in various fields such as catalysis, gas/energy storage, chemical sensing, and drug delivery. However, the low conductivity of most MOFs greatly hinders their development. Therefore, the conductive properties of MOFs need to be strategically modulated to achieve optimal performance and realize broad and practical applications. Although most MOFs possess poor conductivity, several sorts of materials in this class exhibit outstanding conductivity and high charge mobility. In this review, the multifarious strategies and recent progress used to improve the electronic and ionic conductivities of MOFs, including the conductive mechanisms and conductivity measurements are summarized and highlighted. In addition, the important breakthroughs, challenges and future trends of MOF-based conductors are also discussed. (C) 2021 Elsevier B.V. All rights reserved.
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