The excursion covered for the elimination of chromate by exploring the coordination mechanisms between chromium species and various functional groups

Highly efficient elimination of anionic chromate remains a critical task from the biological and ecological perspective owing to their carcinogenic effects on the biosphere and ecosphere. In literature, varieties of functional materials have been applied to remove Cr(VI) from the environmental sources. In which the chemical reduction of Cr(VI) to Cr(III) by a reductant and simultaneous adsorption of Cr species is an effective technique for the removal of Cr(VI). Many effective reductants were applied in the past years, which could be categorized according to their active functional atom/group. Although very few studies illustrated the complete coordination mechanisms between Cr ions and functional groups during the reduction coupled adsorption. This review focuses on recently investigated Cr(VI) reduction coupled adsorption systems based on the electron donor (reductant) functionalities with the interactions of Cr2O72 , CrO42 and Cr3+ ions by the metal and nonmetal functional groups. Also, the removal capacity and equilibrium time were analyzed based on the findings from isotherm and kinetic studies. To conclude, we offered our insights based on the coordination of chromium species with various functionalities into future research prospects and issues in the hope of motivating more researchers to involve in this new area of functional materials for environmental pollution control. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

The efficient elimination of anionic chromate is crucial due to its carcinogenic effects on the environment. Chemical reduction and simultaneous adsorption of Cr(VI) by functional materials is an effective technique. This review focuses on recent research on Cr(VI) reduction coupled adsorption systems based on electron donor functionalities, analyzing the coordination mechanisms and removal capacity.