期刊
COORDINATION CHEMISTRY REVIEWS
卷 438, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2021.213873
关键词
COFs; Ionic; Conduction; Separation; Catalysis; Sensing
资金
- National Natural Science Foundation of China [21971126]
- 111 Project [12015]
iCOFs are an emerging type of crystalline organic polymers that consist of the ionic skeleton and corresponding counterions. They combine the benefits of both porous ionic polymers and COFs, demonstrating great potential in ion conduction, adsorption, separation, catalysis, and sensing. Opportunities and challenges of iCOFs were analyzed in detail for understanding future prospects.
Ionic covalent organic frameworks (iCOFs) are an emerging type of crystalline organic polymers that consist of the ionic skeleton and corresponding counterions. As a joint subgroup of porous ionic polymers (PiPs) and COFs, iCOFs can combine the benefits of both PiPs and COFs. Thus, iCOFs demonstrate great potential in many application fields such as ion conduction, life science, adsorption, separation, catalysis, and sensing. In this context, this review straightens the thread of thought toward this seductive material. A comprehensive introduction was expanded in all kinds of synthesis methods, classification features, and application potential. Finally, the opportunities and challenges of iCOFs were analyzed in detail to understand the future developing prospects deeply. (C) 2021 Elsevier B.V. All rights reserved.
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