期刊
COMPOSITES PART B-ENGINEERING
卷 216, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2021.108883
关键词
Ultrahigh-rate and ultralong-life anode; Core-bishell nanoporous structure; Lithium ion battery; Dealloying; DFT calculations
资金
- National Natural Science Foundation of China [52075351, 51604177]
- National Key Research and Development Program of China [2019YFA0705701]
- International S&T Innovation Cooperation Program of Sichuan Province [2020YFH0039]
- Chengdu International S&T Cooperation Funded Project [2019-GH02-00015-HZ, 2020-GH02-00006-HZ]
- 1000 Talents Plan of Sichuan Province
- Experimental Technology Project of Sichuan University [SCU201078]
- Talent Introduction Program of Sichuan University [YJ201410]
The study successfully developed a 3D core-shell nanoporous electrode with Cu core and bi-layered Cu2O@PANI shells, achieving superior rate capability and ultralong cyclability for advanced LIBs. The electrode design and in-situ formation of Cu2O on NPC matrix played a crucial role in enhancing the performance, while conformal coating of PANI improved Li+ diffusivity and electron conductivity. This work provides novel insights for the design and synthesis of high-rate and long-life nanostructured anodes for advanced LIBs.
Developing efficient electrodes with superior rate performance and superb cyclability are highly desired for meeting urgent demand of high-energy and large-rate lithium ion batteries (LIBs). Electrochemical performance of popular transition metal oxide electrodes is severely restricted by its inferior structure stability and low conductivity, leading to rapid capacity fade at high current density or deep cycling. Herein, a unique 3D corebishell (3D-CBS) nanoporous electrode with configuration of Cu (NPC) core and bi-layered conformal Cu2O@PANI shells was dedicatedly designed and built by a novel and cost-effective approach combining chemical dealloying with controlled electro-polymerization. The 3D-CBS nanoporous electrodes deliver a large reversible capacity of 349 mAh g- 1 at 6000 mA g- 1 after 11500 ultralong-cycles with 76% capacity retention, corresponding to only 0.002% capacity fade per cycle. The superb cyclability is related to the unique 3D-CBS electrode design and in-situ formation of Cu2O with exposed most Cu+ (Cu+/O2- = 4/1) and low-energy (111) crystal plane (0.046 eV/?2) on NPC matrix, as confirmed by physicochemical characterization and DFT calculation. Impressively, the 3D-CBS electrode displays superior rate capability with negligible capacity fade after 5 multistep-rate periods from 2 up to 20 A g-1 and back again to 2 A g-1 repeatedly (over 400 cycles), which is ascribed to the conformal coating of PANI as protective nanolayers with good conductivity on Cu2O, achieving ultrafast Li+ diffusivity (DLi = 2.42 ? 10-10 cm2 s- 1) and significantly improved electron conductivity (82000 S m-1). We believe that this work provides novel insights for design and synthesis of ultrahigh-rate and ultralonglife nanostructured anodes toward advanced LIBs.
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