期刊
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
卷 145, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2021.106384
关键词
Polymer-matrix composites; Electrical properties; Nanofibers; Sepiolite
资金
- Innovation Platform Project of Hunan Provincial Department of Education [19K085]
- National Natural Science Foundation of China [52002404]
This study investigated the application of natural sepiolite nanofibers as a dispersion supporter for polypyrrole in PVDF-based nanocomposites. The experimental results showed that the addition of PPy@Sep nanofibers promoted PVDF crystallization and enhanced the dielectric constant of the composite materials.
In this paper, the natural sepiolite nanofibers (Sep) were selected to be as the dispersion supporter of conductive polymer polypyrrole (PPy) owing to low cost, natural nanowires and well dispersibility in the PVDF matrix. The one-dimensional core-shell polypyrrole/sepiolite (PPy@Sep) nanofibers were synthesized by in-situ polymerization and subsequently introduced into the PVDF matrix by the solution blending method. The experimental results demonstrated that PPy was uniformly coated on the Sep surface. The PPy@Sep nanofibers could disperse in PVDF matrix well and produce the effect of heterogeneous nucleation on PVDF crystallization. With the increasing content of PPy@Sep from 1 wt% to 5 wt%, the dielectric constant of PVDF-based nanocomposites improved from 12 to 40 at 100 Hz because of the hierarchical interfacial polarization originating from the PPy/ Sep interface and PPy/PVDF interface and microcapacitor effect. Meanwhile, a low dielectric loss was observed in the nanocomposites.
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