期刊
COMBUSTION AND FLAME
卷 235, 期 -, 页码 -出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.combustflame.2021.111692
关键词
Kinetic model; Soot growth mechanism; PAH; pi-radicals; Open-shell diradicals
类别
资金
- MIUR with the PRIN 2017 [2017PJ5XXX]
Recent evidence supports resonantly-stabilized radicals as key players in the growth of PAHs. Under combustion conditions, odd-C-numbered PAHs lose hydrogen atoms to form resonantly-stabilized radicals, while even-C-numbered PAHs react as open-shell molecules. The kinetic model incorporating these findings helps to interpret experimental data and contribute to existing chemical kinetic mechanisms.
The mechanism of evolution of polycyclic aromatic hydrocarbons (PAHs) into carbonaceous particles in combustion, atmosphere, and interstellar space has been the subject of intense debate. Recently, there has been emerging evidence supporting resonantly-stabilized radicals as key players in PAH growth. In this work, we build on this hypothesis and propose that, beyond a critical size, PAH reactivity can be assimilated to that of radicals. We found that odd-C-numbered PAHs embedding 5-membered rings rapidly lose a hydrogen atom to form resonantly-stabilized radicals in combustion conditions, while even-C-numbered PAHs react as open-shell rather than closed-shell molecules independently of temperature, as usually assumed. Acenes were used as molecular models of large even-C-numbered PAHs. The construction of a kinetic model including these findings allows to interpret experimental soot oxidation data otherwise irreconcilable with existing chemical kinetic mechanisms. (C) 2021 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
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