期刊
CHINESE CHEMICAL LETTERS
卷 33, 期 3, 页码 1519-1523出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2021.08.125
关键词
beta-O-4 Linkage; Lignin; C-O bond cleavage; Cross-coupling reaction; Palladium-catalyzed
资金
- National Natural Science Foundation of China (NSFC) [21971093]
- International Joint Research Centre for Green Catalysis and Synthesis [2016B01017, 18JR4RA003]
- 111 project
- E.B. Eddy Endowment Fund
Lignin, as a component of lignocellulosic biomass, poses a great challenge for degradation and utilization due to its strong and stable linkages. A cleavage/cross-coupling strategy has been developed to convert lignin model compounds into high value-added compounds. This study presents a palladium-catalyzed cleavage/cross-coupling reaction for the preparation of benzyl amine compounds and phenols through dual C-O bond cleavage.
Lignin is the most recalcitrant of the three components of lignocellulosic biomass. The strength and stability of the linkages have long been a great challenge for the degradation and valorization of lignin biomass to obtain bio-fuels and commercial chemicals. Up to now, the selective cleavage of C-O linkages of lignin to afford chemicals contains only C, H and O atoms. Our group has developed a cleavage/cross-coupling strategy for converting 4-O-5 linkage lignin model compounds into high value-added compounds. Herein, we present a palladium-catalyzed cleavage/cross-coupling of the beta-O-4 lignin model compounds with amines via dual C-O bond cleavage for the preparation of benzyl amine compounds and phenols. (C) 2021 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
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