期刊
CHINESE CHEMICAL LETTERS
卷 33, 期 2, 页码 825-829出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2021.07.033
关键词
1,3-Dipolar cycloaddition; Polypyrazole; Self-assembly; Cyclic polymers
资金
- National Natural Science Foundation of China [21504025]
- Natural Science Foundation of Fujian Province [2019J05040]
- Fujian Provincial Department of Education [JT180038]
- Talent program [GXRC18041]
- Fuzhou University
A one-step method for preparing cyclic polypyrazoles was reported, and the cyclic structure of polypyrazoles was successfully synthesized and confirmed. The cyclic polypyrazoles can self-assemble into vesicles during the reprecipitation process.
The synthesis of cyclic polymer is an important topic in polymer chemistry. Herein, we report a one-step method to prepare cyclic polypyrazoles. Monomers with two functional groups, diazo and alkyne, were synthesized and polymerized via 1,3-diploar cycloaddition in bulk under heating without any catalyst. Polypyrazoles with molecular weights in the range of 3800-4400 g/mol and yields in the range of 78.8-98.7% were successfully synthesized. No chain end group was detected by LC-QTOF-MS and FTIR, which proves the cyclic structure of polypyrazoles. What is noteworthy is that the cyclic polypyrazoles can self-assemble into vesicles during the reprecipitation process, which was proved by the results of SEM and TEM. The reason for that is the formation of intermolecular hydrogen bond between NH and ester groups. (C) 2021 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
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