Enhanced activity of vanadia supported on microporous titania for the selective catalytic reduction of NO with NH3: Effect of promoters

Vanadium oxide-based catalysts are considered a promising catalyst for selective catalytic reduction (SCR) of NO with NH3, which is an effective NOx removal technology. As environmental issues have garnered more attention, however, improvements to vanadium-based SCR catalysts are strongly required. In a previous study, we found that vanadium oxide on microporous titania as a support (V/MPTiO2) has certain advantages, such as improved thermal stability and more suppressed N2O formation, over the use of conventional nanoparticle titania (DT-51) as a support. In this study, widely used promoters, such as W, Sb, and Mo, were added to V/MPTiO2 to investigate whether they have promoting effects on V/MPTiO2 as well. Among these promoters added catalysts, the Wand Mo were found to have significant promoting effects on the enhancement of deNO(x) activities at low temperatures, while the addition of Sb to V/MPTiO2 tended to have a negative effect on the SCR activity. Based on the characterizations, including laser Raman, H-2-temperature programmed reduction (H-2-TPR), and in situ diffuse reflectance infrared Fourier transform (in situ DRIFT) analysis, we found that the addition of W and Mo increased the degree of polymerization in V/MPTiO2, which generated more reactive vanadia species. Hence, such changes, resulting from the addition of Wand Mo promoters to V/MPTiO2, yielded enhanced catalytic activity at low temperatures. (C) 2021 Elsevier Ltd. All rights reserved.

Automated summary

Vanadium oxide-based catalysts, such as V/MPTiO2, are promising for SCR of NO with NH3. Addition of W and Mo as promoters to V/MPTiO2 can enhance deNO(x) activities at low temperatures, while Sb tends to have a negative effect on SCR activity. The addition of W and Mo increases the polymerization in V/MPTiO2, generating more reactive vanadia species and leading to enhanced catalytic activity at low temperatures.