4.6 Article

Borylation and Stannylation Reactions with Tuning of Lewis Acidity

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Synthetic Chemistry with Lewis Acidity-Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross-Couplings

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Summary: Recent advances in the synthesis of organoboron compounds with diminished boron Lewis acidity via B(aam)- and B(dan)-installing borylation reactions have attracted growing attention due to their unique reactivity and outstanding stability toward air and moisture. Direct Suzuki-Miyaura cross-couplings with previously believed unreactive R-B(aam)/B(dan) compounds have also been discussed.

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